{μ-Bis(1-methylimidazol-2-yl)methane-κ2N3:N3′}bis{[(1-methylimidazol-2-yl)methane-κ2N3,N3′]copper(I)} bis(trifluoromethanesulfonate)
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چکیده
منابع مشابه
Trispyrazol-1-ylmethane
In the title compound, C(10)H(10)N(6), the three N atoms in the 2-positions of the pyrazole rings (the ones not bridging to the central C atom are acceptors for weak C-H⋯N contacts with H⋯N distances ranging from 2.49 to 2.59 Å). These furnish the formation of layers perpendicular to [100]. An ortho-rhom-bic polymorph of the title compound has already been described [McLauchlan et al. (2004 ▶)....
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The Ln(III) complexes (Ln = Pr, Nd, Sm and Tb) of the tripodal ligand bis[(2-pyridyl)methyl][(1methylimidazol-2-yl)methyl]amine (bpia) have been synthesized and characterized by single crystal X-ray structure determination as well as vibrational spectroscopy. The coordination spheres of the lanthanide cations are completed by three chelating nitrate anions yielding neutral complexes with a tenf...
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The title complex, [Ni(C(10)H(10)N(6))(2)][Ni(CN)(4)]·2H(2)O, contains an octa-hedral nickel(II) cation and a square-planar nickel(II) anion. Both the cation and the anion reside on a crystallographic center of inversion. The Ni(II) center in the cation is coordinated by six pyrazol-1-yl rings of two chelating tripyrazol-1-ylmethane [HC(pz)(3)] ligands, with Ni-N distances that range between 2....
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The interaction of 3,3-bis(1-methylimidazol-2-yl)propionate (BIMP) with dimethyltin(IV) dichloride (DMT), dibutyltin(IV) dichloride (DBT), and diphenyltin(IV) dichloride (DPT) is investigated at 25°C and 0.1 M ionic strength in water for dimethyltin(IV), and in a 50% dioxane-water mixture for dibutyltin(IV) and diphenyltin(IV). The stepwise formation constants of the 1 : 1 and 1 : 2 complexes f...
متن کاملPoly[(μ-2-acetoxybenzoato)(2-acetoxybenzoato)-μ-aqua-mercury(II)]
In the title compound, [Hg(C(9)H(7)O(4))(2)(H(2)O)](n), the Hg(II) ion is five-coordinated by three acetylsalicylate anions and water leading to the formation of a coordination polymer extending parallel to (001). O-H⋯O and C-H⋯O hydrogen bonds are effective in the stabilization of the crystal structure.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809039622